Skvortsov Dmitry, Lee Seung Jun, Choi Myong Yong, Vilesov Andrey F
Department of Chemistry, University of Southern California, Los Angeles, California 90089, USA.
J Phys Chem A. 2009 Jul 2;113(26):7360-5. doi: 10.1021/jp811497c.
In this work, infrared laser spectroscopy in helium droplets is used to study the solvation of HCl with small water clusters. Clusters of HCl(H(2)O)(n) with n = 1-3 and (HCl)(2)H(2)O have been identified in the free OH stretching spectral range of 3680-3820 cm(-1). The assignment of the infrared vibrational bands of the clusters is aided by ab initio calculations.
在这项工作中，利用氦滴中的红外激光光谱研究了HCl与小水团簇的溶剂化作用。在3680 - 3820 cm⁻¹的自由OH伸缩光谱范围内，已鉴定出n = 1 - 3的HCl(H₂O)ₙ团簇和(HCl)₂H₂O。团簇红外振动带的归属通过从头算计算得到辅助。
