C-H bond activation of decamethylcobaltocene mediated by a nitrogenase Fe(8)S(7) P-cluster model.
作者信息
Ohki Yasuhiro, Murata Ayuro, Imada Motosuke, Tatsumi Kazuyuki
机构信息
Department of Chemistry, Graduate School of Science, and Research Center for Materials Science, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8602, Japan.
出版信息
Inorg Chem. 2009 May 18;48(10):4271-3. doi: 10.1021/ic900284f.
PMID:19341307
Abstract
A C-H bond of Cp*(2)Co was found to be cleaved by a [Fe(8)S(7)] cluster model of the nitrogenase P-cluster. This is the first example of C-H bond activation mediated by a biologically relevant Fe/S cluster. The reaction mechanism probably consists of electron transfer from Cp*(2)Co to the [Fe(8)S(7)] cluster and subsequent proton abstraction by the reduced form of the cluster.
摘要
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