An organogel system can control the stereochemical course of anthracene photodimerization.
作者信息
Dawn Arnab, Fujita Norifumi, Haraguchi Shuichi, Sada Kazuki, Shinkai Seiji
机构信息
Department of Chemistry, Graduate School of Engineering, Kyushu University, Fukuoka 819-0395, Japan.
出版信息
Chem Commun (Camb). 2009 Apr 28(16):2100-2. doi: 10.1039/b820565e. Epub 2009 Feb 9.
DOI:10.1039/b820565e
PMID:19360159
Abstract
A novel photoresponsive organogel with a binary gelator containing 2-anthracenecarboxylic acid shows a high degree of stereochemical control, resulting in head-to-head photocyclodimers exclusively together with significant enantiomeric excess induced by the chiral counterpart of the gelator.
摘要
Zotero 插件