卤键驱动哌嗪环芳自组装形成管状结构。
Halogen bonding drives the self-assembly of piperazine cyclophanes into tubular structures.
作者信息
Raatikainen Kari, Huuskonen Juhani, Lahtinen Manu, Metrangolo Pierangelo, Rissanen Kari
机构信息
Nanoscience Center, Department of Chemistry, University of Jyväskylä, P.O. Box 35, FIN-40014 University of Jyväskylä, Finland.
出版信息
Chem Commun (Camb). 2009 Apr 28(16):2160-2. doi: 10.1039/b901473j. Epub 2009 Mar 12.
DOI:10.1039/b901473j
PMID:19360179
Abstract
Halogen bonding with 1,4-diiodotetrafluorobenzene leads to the self-assembly of piperazine cyclophanes into well-defined tubular structures with solvent inclusion.
摘要
与1,4 - 二碘四氟苯形成的卤键作用致使哌嗪环芳自组装成具有溶剂包合的明确管状结构。
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