5-羟基-10,15,25,30-四（五氟苯基）取代的[26]六卟啉（1.1.1.1.1.1）的同双金属和异双金属配合物

Homo- and heterobismetal complexes of 5-Hydroxy-10,15,25,30-tetrakis(pentafluorophenyl)-substituted [26]hexaphyrin(1.1.1.1.1.1).

作者信息

Koide Taro, Kashiwazaki Gengo, Furukawa Ko, Osuka Atsuhiro

机构信息

Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo-ku, Kyoto 606-8502, Japan.

出版信息

Inorg Chem. 2009 Jun 1;48(11):4595-7. doi: 10.1021/ic900084p.

DOI:10.1021/ic900084p

PMID:19361161

Abstract

Metalation of meso-free 5,10,20,25-tetrakis(pentafluorophenyl)-substituted [26]hexaphyrin(1.1.1.1.1.1) (4) with Cu(II) and Zn(II) ions afforded homodinuclear complexes 6 and 7, respectively. A demetalation-remetalation protocol provided monozinc(II) complex 9 selectively, from which copper(II)-zinc(II) heterodinuclear complex 10 was prepared effectively.

摘要

将无中位的5,10,20,25-四（五氟苯基）取代的[26]六卟啉（1.1.1.1.1.1）（4）与铜（II）和锌（II）离子进行金属化反应，分别得到同双核配合物6和7。通过脱金属-再金属化方案选择性地得到单锌（II）配合物9，由此有效地制备了铜（II）-锌（II）异双核配合物10。