内消旋芳基取代六卟啉的双铜配合物：山墙结构与不同的反铁磁耦合

Biscopper complexes of meso-aryl-substituted hexaphyrin: gable structures and varying antiferromagnetic coupling.

作者信息

Shimizu Soji, Anand Venkataramanarao G, Taniguchi Ryuichiro, Furukawa Ko, Kato Tatsuhisa, Yokoyama Toshihiko, Osuka Atsuhiro

机构信息

Department of Chemistry, Graduate School of Science, Kyoto University, and Core Research for Evolutional Science and Technology (CREST), Japan Science and Technology Agency, Sakyo-ku, Kyoto 606-8502, Japan.

出版信息

J Am Chem Soc. 2004 Oct 6;126(39):12280-1. doi: 10.1021/ja046102x.

DOI:10.1021/ja046102x

PMID:15453757

Abstract

The copper metalation into the hexaphyrins is accompanied by large structural changes to give four complexes exhibiting gable structures and varying antiferromagnetic couplings.

摘要

铜嵌入六卟啉的过程伴随着巨大的结构变化，从而产生了四种具有山墙结构且反铁磁耦合各异的配合物。