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离子液体辅助声化学合成碳纳米管基纳米杂化物:结构与界面特性的调控

Ionic-liquid-assisted sonochemical synthesis of carbon-nanotube-based nanohybrids: control in the structures and interfacial characteristics.

作者信息

Park Ho Seok, Choi Bong Gill, Yang Seong Ho, Shin Weon Ho, Kang Jeung Ku, Jung Doohwan, Hong Won Hi

机构信息

Department of Chemsitry and Biomolecular Engineering (BK 21), Korea Advanced Institute of Science and Technology, Yuseong-gu, Daejeon, 305-701, Republic of Korea.

出版信息

Small. 2009 Aug 3;5(15):1754-60. doi: 10.1002/smll.200900128.

Abstract

A versatile, facile, and rapid synthetic method of advanced carbon nanotube (CNT)-based nanohybrid fabrication, or the so-called ionic-liquid-assisted sonochemical method (ILASM), which combines the supramolecular chemistry between ionic liquids (ILs) and CNTs with sonochemistry for the control in the size and amount of uniformly decorated nanoparticles (NPs) and interfacial engineering, is reported. The excellence in electrocatalysis of hybrid materials with well-designed nanostructures and favorable interfaces is demonstrated by applying them to electrochemical catalysis. The synthetic method discussed in this report has an important and immediate impact not only on the design and synthesis of functional hybrid nanomaterials by supramolecular chemistry and sonochemistry but also on applications of the same into electrochemical devices such as sensors, fuel cells, solar cells, actuators, batteries, and capacitors.

摘要

报道了一种通用、简便且快速的基于先进碳纳米管(CNT)的纳米杂化材料制备合成方法,即所谓的离子液体辅助声化学法(ILASM),该方法将离子液体(ILs)与碳纳米管之间的超分子化学与声化学相结合,用于控制均匀修饰的纳米颗粒(NPs)的尺寸和数量以及界面工程。通过将具有精心设计的纳米结构和良好界面的杂化材料应用于电化学催化,证明了其在电催化方面的卓越性能。本报告中讨论的合成方法不仅对通过超分子化学和声化学设计和合成功能性杂化纳米材料具有重要且直接的影响,而且对其在诸如传感器、燃料电池、太阳能电池、致动器、电池和电容器等电化学装置中的应用也具有重要且直接的影响。

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