基于萘并咪唑二酮和硼酸的A-D-A传感器作为水中的开启型氰化物探针。
A-D-A sensors based on naphthoimidazoledione and boronic acid as turn-on cyanide probes in water.
作者信息
Jamkratoke Matinee, Ruangpornvisuti Vithaya, Tumcharern Gamolwan, Tuntulani Thawatchai, Tomapatanaget Boosayarat
机构信息
Supramolecular Chemistry Research Unit, Department of Chemistry, Faculty of Science, Chulalongkorn University, Bangkok 10330, Thailand.
出版信息
J Org Chem. 2009 May 15;74(10):3919-22. doi: 10.1021/jo900170r.
PMID:19371098
Abstract
Three fluorescence sensors based on naphthoquinoneimidazole and boronic acid (A-D-A system) have been developed with high selectivity for cyanide in water. The fluorescence band at 460 nm was switched on upon substitution of cyanide on sensors in the CTAB micelle.
摘要
已经开发出三种基于萘醌咪唑和硼酸（A-D-A体系）的荧光传感器，它们对水中的氰化物具有高选择性。在CTAB胶束中，当氰化物取代传感器上的基团时，460nm处的荧光带被开启。
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