Yamada Teppei, Kitagawa Hiroshi
Department of Chemistry, Faculty of Science, Kyushu University, Hakozaki 6-10-1, Higashi-ku, Fukuoka 812-8581, Japan.
J Am Chem Soc. 2009 May 13;131(18):6312-3. doi: 10.1021/ja809352y.
A noncoordinating hydroxyl group was introduced into a metal-organic framework (MOF) by a procedure involving a protection, complexation, and deprotection (PCD) reaction sequence, and the crystal structure of a novel MOF, [Zn(dhybdc)(bpy)] x 4 DMF (1), was determined. 1 did not have an interpenetrated structure. The three-dimensional pores had large apertures. Results showed that the PCD method is a novel synthetic method for the introduction of various functional groups into MOFs.
通过涉及保护、络合和脱保护（PCD）反应序列的过程，将一个非配位羟基引入到金属有机框架（MOF）中，并确定了一种新型MOF [Zn(dhybdc)(bpy)] x 4 DMF（1）的晶体结构。1不具有互穿结构。三维孔具有较大的孔径。结果表明，PCD方法是一种将各种官能团引入MOF的新型合成方法。
