高价碘催化酮羧酸氧化内酯化生成酮内酯。
Hypervalent iodine-catalyzed oxylactonization of ketocarboxylic acids to ketolactones.
作者信息
Uyanik Muhammet, Yasui Takeshi, Ishihara Kazuaki
机构信息
Graduate School of Engineering, Nagoya University, Chikusa, Nagoya 464-8603, Japan.
出版信息
Bioorg Med Chem Lett. 2009 Jul 15;19(14):3848-51. doi: 10.1016/j.bmcl.2009.03.148. Epub 2009 Apr 5.
PMID:19376702
Abstract
The hypervalent iodine-catalyzed oxylactonization of ketocarboxylic acids to ketolactones was achieved in the presence of iodobenzene (10 mol%), p-toluenesulfonic acid monohydrate (20 mol%) and meta-chloroperbenzoic acid as a stoichiometric co-oxidant.
摘要
在碘苯（10 mol%）、一水合对甲苯磺酸（20 mol%）和间氯过氧苯甲酸作为化学计量的共氧化剂存在的情况下，实现了高价碘催化酮羧酸氧化内酯化生成酮内酯。
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