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缠结单分散聚合物熔体拉伸过程中弹性破裂的模拟。

Simulation of elastic rupture in extension of entangled monodisperse polymer melts.

作者信息

Lyhne Anders, Rasmussen Henrik Koblitz, Hassager Ole

机构信息

Department of Chemical and Biochemical Engineering, Danish Polymer Center, Technical University of Denmark, 2800 Kgs. Lyngby, Denmark.

出版信息

Phys Rev Lett. 2009 Apr 3;102(13):138301. doi: 10.1103/PhysRevLett.102.138301. Epub 2009 Apr 2.

Abstract

We use a Lagrangian finite element method to simulate experiments on continued and interrupted extensions of a highly entangled monodisperse polymer melt. It is demonstrated that delayed sample necking or rupture may be explained in terms of the original Doi-Edwards model augmented by the mechanism of chain stretching alone.

摘要

我们使用拉格朗日有限元方法来模拟高度缠结的单分散聚合物熔体连续和间断拉伸的实验。结果表明,延迟的样品颈缩或破裂可以仅通过链拉伸机制增强的原始Doi-Edwards模型来解释。

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