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Gd2O3:0.05 Eu微晶的取向单层膜:氢氧化物膜的准拓扑转变及光致发光性能的显著增强。

Oriented monolayer film of Gd2O3:0.05 Eu crystallites: quasi-topotactic transformation of the hydroxide film and drastic enhancement of photoluminescence properties.

作者信息

Hu Linfeng, Ma Renzhi, Ozawa Tadashi C, Sasaki Takayoshi

机构信息

International Center for Materials Nanoarchitectonics, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan.

出版信息

Angew Chem Int Ed Engl. 2009;48(21):3846-9. doi: 10.1002/anie.200806206.

Abstract

Caught on film: A semitransparent and intensely luminescent monolayer film of oriented Gd(2)O(3):0.05 Eu platelet crystallites is fabricated by annealing the precursor hydroxide film (see scheme). The photoluminescence properties of the as-transformed film are greatly improved over those of the hydroxide film, and are much more pronounced than those of the corresponding Gd(2)O(3):0.05 Eu powder.

摘要

拍摄到

通过对前驱体氢氧化物薄膜进行退火处理,制备出了由取向的Gd₂O₃:0.05 Eu片状微晶组成的半透明且强烈发光的单层薄膜(见图例)。转化后的薄膜的光致发光性能相较于氢氧化物薄膜有了极大提升,且比相应的Gd₂O₃:0.05 Eu粉末更为显著。

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