Gu Y J, Chen Q F, Cai L C, Chen Z Y, Zheng J, Jing F Q
National Key Laboratory of Shock Wave and Detonation Physics Research, Institute of Fluid Physics, P.O. Box 919-102, Mianyang, Sichuan 621900, People's Republic of China.
J Chem Phys. 2009 May 14;130(18):184506. doi: 10.1063/1.3124562.
Time-resolved spectral radiation histories of the gaseous H(2) + He mixtures under shock loadings were measured by using a six-wavelength channel pyrometer. The initial gaseous mixtures had a mole component of H(2):He = 1:1.21, which were shocked from room temperature and initial pressure of 20 MPa to a pressure range of 1-30 GPa and temperature range of 3000-7000 K by means of a two-stage light-gas gun. Multishock reverberations between the base-plate and sapphire window can be observed up to the fifth-shock compressions. The experimental data are in good agreement with self-consistent fluid variational theory calculations in which the dissociation process of hydrogen molecules and various interactions among atomic and molecular species are taken into account.
利用六波长通道高温计测量了冲击载荷下气态H₂ + He混合物的时间分辨光谱辐射历史。初始气态混合物的摩尔组分为H₂:He = 1:1.21,通过两级轻气炮将其从室温及20 MPa的初始压力冲击至1 - 30 GPa的压力范围和3000 - 7000 K的温度范围。在基板和蓝宝石窗口之间可观察到多达五次冲击压缩的多次冲击回响。实验数据与自洽流体变分理论计算结果吻合良好,该计算考虑了氢分子的离解过程以及原子和分子物种之间的各种相互作用。