Yan Yun, Lu Ting, Huang Jianbin
Beijing National Laboratory for Molecular Science, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, People's Republic of China.
J Colloid Interface Sci. 2009 Sep 1;337(1):1-10. doi: 10.1016/j.jcis.2009.04.082. Epub 2009 May 12.
Researches on the bolaamphiphiles have attracted considerable attentions in the last three decades. Among which, the mixed systems with conventional surfactants are of special interest. This review focuses on the recent advances in the research of the bolaamphiphile/oppositely charged conventional surfactant mixed systems. The following contents are covered: (1) surface properties, which include (i) the general properties of the mixed systems, (ii) the effect of rigid group on the surface properties, and (iii) the slow adsorption process of bolaamphiphiles on solid surface; (2) aggregation behaviors in the bulk solution, including (i) the superior vesicle formation ability, (ii) superior vesicle stability, (iii) dynamic morphology of the aggregates, and (iv) tunable morphologies; (3) perspective for the future.
在过去三十年中，对双性两亲分子的研究引起了相当大的关注。其中，与传统表面活性剂的混合体系特别受关注。本综述聚焦于双性两亲分子/带相反电荷的传统表面活性剂混合体系研究的最新进展。涵盖以下内容：（1）表面性质，包括（i）混合体系的一般性质，（ii）刚性基团对表面性质的影响，以及（iii）双性两亲分子在固体表面的缓慢吸附过程；（2）本体溶液中的聚集行为，包括（i）卓越的囊泡形成能力，（ii）卓越的囊泡稳定性，（iii）聚集体的动态形态，以及（iv）可调控的形态；（3）未来展望。
