在水溶液中使用2-氯咪唑啉鎓盐将未保护的糖一步转化为β-糖基叠氮化物。
One-step conversion of unprotected sugars to beta-glycosyl azides using 2-chloroimidazolinium salt in aqueous solution.
作者信息
Tanaka Tomonari, Nagai Hikaru, Noguchi Masato, Kobayashi Atsushi, Shoda Shin-Ichiro
机构信息
Department of Biomolecular Engineering, Graduate School of Engineering, Tohoku University, Aoba, Sendai, Miyagi 980-8579, Japan.
出版信息
Chem Commun (Camb). 2009 Jun 21(23):3378-9. doi: 10.1039/b905761g. Epub 2009 May 13.
DOI:10.1039/b905761g
PMID:19503876
Abstract
Various beta-glycosyl azides have been synthesized directly in water by the reaction of unprotected sugars and sodium azide mediated by 2-chloro-1,3-dimethylimidazolinium chloride (DMC).
摘要
通过2-氯-1,3-二甲基咪唑鎓氯化物（DMC）介导的未保护糖与叠氮化钠的反应，已直接在水中合成了各种β-糖基叠氮化物。
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