用于氮氧自由基介导聚合反应的先进超分子引发剂，兼具金属离子配位和氢键位点。
Advanced supramolecular initiator for nitroxide-mediated polymerizations containing both metal-ion coordination and hydrogen-bonding sites.
作者信息
Mansfeld Ulrich, Hager Martin D, Hoogenboom Richard, Ott Christina, Winter Andreas, Schubert Ulrich S
机构信息
Laboratory of Organic and Macromolecular Chemistry, Friedrich-Schiller-Universität Jena, Humboldtstrasse 10, 07743 Jena, Germany.
出版信息
Chem Commun (Camb). 2009 Jun 21(23):3386-8. doi: 10.1039/b902636c. Epub 2009 Apr 24.
DOI:10.1039/b902636c
PMID:19503879
Abstract
The synthesis of a new difunctional nitroxide initiator combining two orthogonal supramolecular entities is reported; controlled radical polymerization of styrene using this initiator is demonstrated to generate well-defined heterotelechelic polymers in a one-step procedure.
摘要
报道了一种结合两个正交超分子实体的新型双功能氮氧化物引发剂的合成；使用该引发剂对苯乙烯进行可控自由基聚合，结果表明能在一步反应中生成结构明确的杂臂端基聚合物。
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