酞菁锂薄膜的电化学结构转变及可逆掺杂/去掺杂
Electrochemical structural transformation and reversible doping/dedoping of lithium phthalocyanine thin films.
作者信息
Inagawa Maya, Yoshikawa Hirofumi, Yokoyama Toshihiko, Awaga Kunio
机构信息
Research Center for Materials Science & Department of Chemistry, Nagoya University, Furo-cho, 464-8602 Chikusa-ku, Nagoya, Japan.
出版信息
Chem Commun (Camb). 2009 Jun 21(23):3389-91. doi: 10.1039/b902903f. Epub 2009 Apr 24.
DOI:10.1039/b902903f
PMID:19503880
Abstract
The alpha-form thin films (120 nm) of lithium phthalocyanine (LiPc) exhibit a structural transformation to the x-form by electrochemical oxidation which introduces the counter anions into the thin films, and these anions are reversibly dedoped by electrochemical re-reduction, maintaining the x-form structure.
摘要
酞菁锂（LiPc）的α型薄膜（120纳米）通过电化学氧化发生结构转变为x型，此过程将抗衡阴离子引入薄膜中，并且这些阴离子通过电化学再还原被可逆地去掺杂，从而维持x型结构。
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