Ahnfeldt Tim, Guillou Nathalie, Gunzelmann Daniel, Margiolaki Irene, Loiseau Thierry, Férey Gérard, Senker Jürgen, Stock Norbert
Institut für Anorganische Chemie, Christian-Albrechts-Universität, Max-Eyth-Strasse 2, 24118 Kiel, Germany.
Angew Chem Int Ed Engl. 2009;48(28):5163-6. doi: 10.1002/anie.200901409.
Al together now! A new stable aluminum aminoterephthalate system contains octameric building blocks that are connected by organic linkers to form a 12-connected net (see picture). The structure adopts a cubic centered packing motive in which octameric units replace individual atoms, thus forming distorted octahedral (red sphere) and tetrahedral cages (green spheres) with effective accessible diameters of 1 and 0.45 nm, respectively.
现在全体集合！一种新的稳定的氨基对苯二甲酸铝体系包含八聚体结构单元，这些结构单元通过有机连接体相连形成一个12连接的网络（见图）。该结构采用体心立方堆积模式，其中八聚体单元取代了单个原子，从而分别形成有效孔径为1纳米和0.45纳米的扭曲八面体笼（红色球体）和四面体笼（绿色球体）。
