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[不同辐照条件下TiO₂/ACF同步脱硫脱硝]

[Simultaneous desulfurization and denitrification by TiO2/ACF under different irradiation].

作者信息

Han Jing, Zhao Yi

机构信息

School of Environmental Science and Engineering, North China Electric Power University, Baoding 071003, China.

出版信息

Huan Jing Ke Xue. 2009 Apr 15;30(4):997-1002.

Abstract

The supported TiO2 photocatalysts were prepared in laboratory, and the experiments of simultaneous desulfurization and denitrification were carried out by self-designed photocatalysis reactor. The optimal experimental conditions were achieved, and the efficiencies of simultaneous desulfurization and denitrification under two different light sources were compared. The results show that the oxygen content of flue gas, reaction temperature, flue gas humidity and irradiation intensity are most essential factors to photocatalysis. For TiO2/ACF, the removal efficiencies of 99.7% for SO2 and 64.3% for NO are obtained respectively at optimal experimental conditions under UV irradiation. For TiO2/ACF, the removal efficiencies of 97.5% for SO2 and 49.6% for NO are achieved respectively at optimal experimental conditions under the visible light irradiation. The results of five times parallel experiments indicate standard deviation S of parallel data is little. The mechanism of removal for SO2 and NO is proposed under two light sources by ion chromatography analysis of the absorption liquid.

摘要

在实验室制备了负载型TiO₂光催化剂,并通过自行设计的光催化反应器进行了同时脱硫脱硝实验。获得了最佳实验条件,并比较了两种不同光源下同时脱硫脱硝的效率。结果表明,烟气含氧量、反应温度、烟气湿度和光照强度是光催化的最关键因素。对于TiO₂/ACF,在紫外光照射下的最佳实验条件下,SO₂和NO的去除效率分别达到99.7%和64.3%。对于TiO₂/ACF,在可见光照射下的最佳实验条件下,SO₂和NO的去除效率分别达到97.5%和49.6%。五次平行实验结果表明平行数据的标准偏差S很小。通过对吸收液进行离子色谱分析,提出了两种光源下SO₂和NO的去除机理。

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