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[预臭氧化对黄浦江微滤的影响]

[Effect of preozonation on microfiltration for Huangpu River].

作者信息

Song Ya-Li, Dong Bing-Zhi, Gao Nai-Yun, Ma Xiao-Yan

机构信息

School of Environmental Science and Engineering, Tongji University, Shanghai 200092, China.

出版信息

Huan Jing Ke Xue. 2009 May 15;30(5):1391-6.

Abstract

This study investigated the effect of preozonation on organic matter and microfiltration membrane filtration, Huangpu River surface water ozonated was filtrated by MF membrane. The results show that highest rejection efficiency of DOC and UVr by ozone are 10% and 71% respectively during 0.5-3.0 mg/L ozone dosage. With increasing of ozone concentration, organic substances of 2 x 10(3)-7 x 10(3) reduce gradually, while organic matter of which less than 0.5 x 10(3) change slightly. Ozone oxidizes more hydrophobic fraction to hydrophilic one and only few to inorganic matter. Changes of organic matter composition affect membrane filtration resistance, thereby improve membrane flux. There is the optimal dosage with ozone of 1.5 mg/L made membrane flux maximum in the range of 0.5-3.0 mg/L ozone dosage. The reason is change of organic matter composition which made membrane filtration resistance minimum in the ozone dosage of 1.5 mg/L.

摘要

本研究考察了预臭氧化对有机物及微滤膜过滤的影响,对经臭氧化处理的黄浦江地表水进行微滤膜过滤。结果表明,在臭氧投加量为0.5 - 3.0 mg/L时,臭氧对溶解性有机碳(DOC)和紫外吸光度值(UVr)的最高去除率分别为10%和71%。随着臭氧浓度的增加,分子量在2×10³ - 7×10³的有机物逐渐减少,而分子量小于0.5×10³的有机物变化不大。臭氧将较多的疏水性组分氧化为亲水性组分,仅有少量被氧化为无机物。有机物组成的变化影响膜过滤阻力,从而提高膜通量。在0.5 - 3.0 mg/L的臭氧投加量范围内,存在臭氧最佳投加量1.5 mg/L使膜通量最大。原因是在臭氧投加量为1.5 mg/L时,有机物组成的变化使膜过滤阻力最小。

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