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[臭氧/混凝预处理对减少膜污染的影响]

[Effect of ozone/coagulation pretreatment on membrane fouling reduction].

作者信息

Song Ya-li, Dong Bing-zhi, Gao Nai-yun, Ma Xiao-yan

机构信息

School of Civil Engineering and Architecture, Zhejiang University of Science and Technology, Hangzhou 310023, China.

出版信息

Huan Jing Ke Xue. 2010 Jul;31(7):1516-9.

Abstract

In order to investigate the effect of ozone and coagulation pretreatments on organic matter and MF membrane filtration, pretreated Huangpu River surface water was filtrated by MF membrane. The results showed that there were the optimal dosages of ozone and coagulant made maximum membrane flux. The result of membrane fouling reduction by coagulation was better than that by ozone, which was relative to character of organic matter removed by two pretreatment processes. Organics in Huangpu River water mostly concentrates in relative molecule mass (Mr) ranging 3 x 10(3)-5 x 10(3). Research on the chemical cleaning of the fouled membrane indicated that fouling organic substance concentrated about Mr 4.5 x 10(3). Removals of Mr 3 x 10(3) organic matter are higher than Mr 5 x 10(3) organic matter by ozone oxidation. Coagulation process can remove 5 x 10(3) high relative molecular mass organic matter effectively. Removal of these organics fouled membrane by coagulation was better than that by ozone, thereby to effectively reduce membrane fouling.

摘要

为了研究臭氧和混凝预处理对有机物及微滤膜过滤的影响,对预处理后的黄浦江地表水进行微滤膜过滤。结果表明,存在臭氧和混凝剂的最佳投加量可使膜通量最大。混凝对膜污染的减轻效果优于臭氧,这与两种预处理工艺去除有机物的特性有关。黄浦江水中的有机物大多集中在相对分子质量(Mr)为3×10³ - 5×10³的范围内。对污染膜的化学清洗研究表明,污染有机物集中在Mr约4.5×10³左右。通过臭氧氧化,Mr为3×10³的有机物去除率高于Mr为5×10³的有机物。混凝工艺能有效去除Mr为5×10³的高相对分子质量有机物。混凝去除这些造成膜污染的有机物的效果优于臭氧,从而有效减轻膜污染。

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