Zhang Shu-Jun, Meng Fan-Neng, Lü Jian, Gan Yi-Ping, Wang Hong-Chen, Peng Yong-Zhen
Key Laboratory of Beijing for Water Quality Science and Water Environmental Recovery Engineering, Beijing University of Technology, Beijing 100022, China.
Huan Jing Ke Xue. 2009 May 15;30(5):1437-41.
The affecting factors and controlling methods of how realizing and maintaining half-nitrosofication of dewatering liquid of digested sludge were investigated in an A/O process. The experimental results showed that the nitritation was obtained in 29 d under bulk liquid temperature of 9-20 degrees C, average DO of 5.4 mg/L, SRT of about 30 d and influent ammonia loading rate of 0.64 kg/(m3 x d). The nitritation with 70% nitrite accumulation efficiency was maintained during 65 d when average FA concentration in A/O reactor was more than 4 mg/L. Furthermore, the half-nitrosofication with effluent ammonia and nitrite ratio of 1:1.32 was obtained. When the ammonia loading rate reduced to 0.19 kg/(m3 x d) (FA < 1 mg/L), the nitritation disappeared, and the high FA as a main factor of maintaining half-nitrosofication was proved again with FISH under the condition of different FA. TN removal concentration was about 91 mg/L under influent COD of 282 mg/L and raw C/N ratio of 0.85 in the A/O system, which due to nitritation saving much carbon sources. The study showed that the half-nitrosofication of the dewatering liquid was obtained and stably maintained when FA was more than 4 mg/L in the A/O reactor by dynamic controlling influent ammonia loading rate and pH value in the system under middle or low temperature, high DO, long SRT.
在A/O工艺中,研究了消化污泥脱水液实现并维持半亚硝化的影响因素及控制方法。实验结果表明,在混合液温度为9 - 20℃、平均溶解氧为5.4mg/L、污泥龄约30d、进水氨氮负荷率为0.64kg/(m³·d)的条件下,29d内实现了亚硝化。当A/O反应器中平均游离氨(FA)浓度大于4mg/L时,亚硝酸盐积累效率为70%的亚硝化在65d内得以维持。此外,还实现了出水氨氮与亚硝酸盐氮比例为1:1.32的半亚硝化。当氨氮负荷率降至0.19kg/(m³·d)(FA < 1mg/L)时,亚硝化消失,在不同FA条件下通过荧光原位杂交(FISH)再次证明高FA是维持半亚硝化的主要因素。在A/O系统中,进水化学需氧量(COD)为282mg/L、原碳氮比为0.85时,总氮(TN)去除浓度约为91mg/L,这是由于亚硝化节省了大量碳源。研究表明,在中低温、高溶解氧、长污泥龄条件下,通过动态控制进水氨氮负荷率和系统pH值,当A/O反应器中FA大于4mg/L时,可实现并稳定维持脱水液的半亚硝化。