1,10-菲咯啉：用于发光分子、材料和金属配合物的多功能结构单元。

1,10-phenanthrolines: versatile building blocks for luminescent molecules, materials and metal complexes.

作者信息

Accorsi Gianluca, Listorti Andrea, Yoosaf K, Armaroli Nicola

机构信息

Molecular Photoscience Group-Istituto per la Sintesi Organica e la Fotoreattivitá (ISOF), Consiglio Nazionale delle Ricerche (CNR), Via Gobetti 101, 40129 Bologna, Italy.

出版信息

Chem Soc Rev. 2009 Jun;38(6):1690-700. doi: 10.1039/b806408n. Epub 2009 Mar 23.

DOI:10.1039/b806408n

PMID:19587962

Abstract

1,10-phenanthroline entails several appealing structural and chemical properties: rigidity, planarity, aromaticity, basicity, chelating capability. This makes it a versatile starting material for synthetic organic, inorganic and supramolecular chemistry. In this tutorial review we examine how the chemical versatility of pristine 1,10-phenanthroline, a weakly fluorescent molecule, has been exploited to design many UV-Vis-NIR luminescent organic derivatives and coordination compounds with transition-metal (Ru(ii), Os(ii), Rh(iii), Cr(iii), Pt(ii), Zn(ii), Cu(i), Ag(i)) and rare-earth (Eu(iii),Tb(iii), Yb(iii), Nd(iii), Er(iii)) cations. They are utilized for many analytical and technological applications.

摘要

1,10-菲咯啉具有多种吸引人的结构和化学性质：刚性、平面性、芳香性、碱性、螯合能力。这使其成为合成有机、无机和超分子化学中一种用途广泛的起始原料。在本教程综述中，我们研究了原始的1,10-菲咯啉（一种弱荧光分子）的化学多功能性是如何被利用来设计许多具有紫外-可见-近红外发光的有机衍生物以及与过渡金属（Ru(ii)、Os(ii)、Rh(iii)、Cr(iii)、Pt(ii)、Zn(ii)、Cu(i)、Ag(i)）和稀土（Eu(iii)、Tb(iii)、Yb(iii)、Nd(iii)、Er(iii)）阳离子的配位化合物。它们被用于许多分析和技术应用中。