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用于高性能有机发光二极管的表面改性纳米管阳极

Surface-modified nanotube anodes for high performance organic light-emitting diode.

作者信息

Ou Eric C-W, Hu Liangbing, Raymond Gan Ching Ruey, Soo Ong Kian, Pan Jisheng, Zheng Zhang, Park Youngbae, Hecht David, Irvin Glen, Drzaic Paul, Gruner George

机构信息

Institute of Materials Research and Engineering, 3 Research Link, 117602, Singapore.

出版信息

ACS Nano. 2009 Aug 25;3(8):2258-64. doi: 10.1021/nn900406n.

Abstract

In this work, we reported high performance OLED devices with transparent and conductive carbon nanotube anodes after modification. The modifications include IMRE proprietary PEDOT:PSS composite top coating (PS(C)), concentrated HNO(3) acid soaking, and polymer encapsulation. For PS(C)-modified nanotube thin film anode, we achieved maximum luminescence of approximately 9000 cd/m(2), close to ITO-based OLED device performance, and high efficiency of approximately 10 cd/A, similar with ITO-based OLED device. The performance is approximately 30 to 450 times better than that achieved for OLED devices using CNT anodes by others. In addition, we also investigate the mechanical property, work function, sheet resistance, and surface morphology of modified carbon nanotube thin-film anodes.

摘要

在这项工作中,我们报道了经过改性后具有透明导电碳纳米管阳极的高性能OLED器件。改性包括IMRE专有的PEDOT:PSS复合顶涂层(PS(C))、浓硝酸浸泡和聚合物封装。对于PS(C)改性的纳米管薄膜阳极,我们实现了约9000 cd/m²的最大发光强度,接近基于ITO的OLED器件性能,以及约10 cd/A的高效率,与基于ITO的OLED器件相似。该性能比其他使用碳纳米管阳极的OLED器件所达到的性能大约好30至450倍。此外,我们还研究了改性碳纳米管薄膜阳极的机械性能、功函数、表面电阻和表面形态。

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