Budarin Vitaly L, Clark James H, Lanigan Brigid A, Shuttleworth Peter, Breeden Simon W, Wilson Ashley J, Macquarrie Duncan J, Milkowski Kris, Jones Jenny, Bridgeman Toby, Ross Andy
Green Chemistry Centre of Excellence, University of York, York YO10 5DD, UK.
Bioresour Technol. 2009 Dec;100(23):6064-8. doi: 10.1016/j.biortech.2009.06.068. Epub 2009 Jul 16.
The low temperature microwave activation of biomass has been investigated as a novel, energy efficient route to bio-oils. The properties of the bio-oil produced were considered in terms of fuel suitability. Water content, elemental composition and calorific value have all been found to be comparable to and in many cases better than conventional pyrolysis oils. Compositional analysis shows further differences with conventional pyrolysis oils including simpler chemical mixtures, which have potential as fuel and chemical intermediates. The use of simple additives, e.g. HCl, H(2)SO(4) and NH(3), affects the process product distribution, along with changes in the chemical composition of the oils. Clearly the use of our low temperature technology gives significant advantages in terms of preparing a product that is much closer to that which is required for transport fuel applications.
生物质的低温微波活化已作为一种生产生物油的新型、节能途径进行了研究。从燃料适用性的角度考虑了所生产生物油的性质。已发现其含水量、元素组成和热值与传统热解油相当,而且在许多情况下优于传统热解油。成分分析表明,与传统热解油还有进一步差异,包括化学混合物更简单,这些混合物有作为燃料和化学中间体的潜力。使用简单添加剂,如HCl、H₂SO₄和NH₃,会影响工艺产物分布以及油的化学成分变化。显然,我们的低温技术在制备更接近运输燃料应用所需产品方面具有显著优势。