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碱性溶液中糖类在金电极和铜电极上的电化学氧化研究进展

Recent progress in electrochemical oxidation of saccharides at gold and copper electrodes in alkaline solutions.

作者信息

Torto Nelson

机构信息

Department of Chemistry, Rhodes University, P. O. Box 94, Grahamstown, 6140 South Africa.

出版信息

Bioelectrochemistry. 2009 Sep;76(1-2):195-200. doi: 10.1016/j.bioelechem.2009.06.009. Epub 2009 Jun 23.

DOI:10.1016/j.bioelechem.2009.06.009
PMID:19617004
Abstract

This article reviews the progress made in the past 10 years, on electrochemical oxidation of saccharides in alkaline media for gold and copper electrodes. The mechanism and processes associated with the electrochemical oxidation of saccharides at native and surface coated electrodes continues to be of great interest. Despite the effort and various mechanisms proposed, still the need for an electrochemically active material that understands the complexity associated with saccharides continues to increase as their detection poses a challenge for bioanalytical chemistry and liquid chromatography.

摘要

本文综述了过去10年中,在碱性介质中糖类在金电极和铜电极上进行电化学氧化的研究进展。在天然电极和表面涂层电极上,与糖类电化学氧化相关的机理和过程一直备受关注。尽管人们付出了努力并提出了各种机理,但由于糖类的检测对生物分析化学和液相色谱构成了挑战,因此对能够理解与糖类相关复杂性的电化学活性材料的需求仍在不断增加。

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