大环配位化合物阴离子结合亲和力的拟别构调节
Pseudo-allosteric regulation of the anion binding affinity of a macrocyclic coordination complex.
作者信息
Kuwabara Junpei, Yoon Hyo Jae, Mirkin Chad A, DiPasquale Antonio G, Rheingold Arnold L
机构信息
Department of Chemistry and the International Institute for Nanotechnology, Northwestern University, 2145 Sheridan Road, Evanston, IL 60208-3113, USA.
出版信息
Chem Commun (Camb). 2009 Aug 14(30):4557-9. doi: 10.1039/b905150c. Epub 2009 Jun 19.
DOI:10.1039/b905150c
PMID:19617982
Abstract
The anion binding affinity of a macrocyclic Rh complex can be allosterically regulated by reaction with a small molecule (an isocyanide), which effects a change in macrocycle size and shape.
摘要
大环铑配合物的阴离子结合亲和力可通过与小分子（异腈）反应进行变构调节，这会导致大环尺寸和形状发生变化。
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