College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, China.
J Hazard Mater. 2009 Nov 15;171(1-3):924-31. doi: 10.1016/j.jhazmat.2009.06.134. Epub 2009 Jul 2.
Pulsed high-voltage discharge as one of the AOTs has generated a lot of interest in its applications to organic contaminants removal. It was demonstrated that some contaminants such as dyes and phenols could be effectively removed by the discharge, which can promote both physical and chemical processes leading to strong UV light, local high temperature, intense shock waves and the formation of chemically active species such as OH, H, O, O(2)(-), HO(2), H(2)O(2), O(3), respectively, etc. The technology was been further developed by the updating of the power supply and the discharge reactor. The formation of active species is one of the crucial factors in the degradation of organic compounds in the pulsed high-voltage discharge system. This paper reviews the literatures on the pulsed power supply, reactor, physical effects, active species formation and mechanism of organic contaminants degradation in the discharge system.
脉冲高压放电作为一种高级氧化技术(AOTs),在有机污染物去除方面的应用引起了广泛关注。研究表明,放电可以有效去除某些污染物,如染料和酚类物质,这是由于放电可以促进物理和化学过程,分别产生强紫外光、局部高温、强烈冲击波以及形成化学活性物质,如 OH、H、O、O(2)(-)、HO(2)、H(2)O(2)、O(3)等。该技术通过更新电源和放电反应器得到进一步发展。活性物质的形成是脉冲高压放电系统中有机化合物降解的关键因素之一。本文综述了关于脉冲电源、反应器、物理效应、活性物质形成以及放电系统中有机污染物降解机制的文献。