Quaternary tin(IV) antimony(III) sulfide decorated with lanthanum(III) ethylenediamine complexes: [La(en)4SbSnS5]2 x 0.5 H2O.

作者信息

Feng Mei-Ling, Ye Dong, Huang Xiao-Ying

机构信息

State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fujian, Fuzhou 350002, People's Republic of China.

出版信息

Inorg Chem. 2009 Sep 7;48(17):8060-2. doi: 10.1021/ic901044k.

DOI:10.1021/ic901044k

PMID:19642620

Abstract

A quaternary tin(IV) antimony(III) sulfide decorated by lanthanum(III) ethylenediamine complexes, namely, La(en)(4)SbSnS(5) x 0.5 H(2)O (1; en = ethylenediamine), has been solvothermally synthesized and structurally, thermally, and optically characterized. Its structure features an isolated hexanuclear molecule of La(en)(4)SbSnS(5). The intermolecule hydrogen-bond interactions result in a three-dimensional supramolecular network, which remains intact upon dehydration.

摘要