[SeO(4){WO(O(2))(2)}(2)](2-)催化过氧化氢高效氧化硫化物
Highly efficient oxidation of sulfides with hydrogen peroxide catalyzed by [SeO(4){WO(O(2))(2)}(2)](2-).
作者信息
Kamata Keigo, Hirano Tomohisa, Mizuno Noritaka
机构信息
Department of Applied Chemistry, School of Engineering, The University of Tokyo, Tokyo, Japan.
出版信息
Chem Commun (Camb). 2009 Jul 14(26):3958-60. doi: 10.1039/b907952a. Epub 2009 Jun 2.
DOI:10.1039/b907952a
PMID:19662265
Abstract
By using the selenium-containing dinuclear peroxotungstate at 0.005-0.1 mol%, various kinds of sulfides could be converted into the corresponding sulfoxides or sulfones in excellent yields with one or two equivalents of H(2)O(2) with respect to the sulfide, respectively.
摘要
通过使用0.005 - 0.1摩尔%的含硒双核过氧钨酸盐，相对于硫化物分别使用一当量或两当量的H₂O₂ ，各种硫化物可以以优异的产率转化为相应的亚砜或砜。
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