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[除草剂苯噻酰草胺在土壤中的吸附与解吸行为]

[Sorption and desorption behavior of the herbicide mefenacet on soils].

作者信息

Liu Zhen-Yu, Guo Hui-Qin, He Huan, Yang Shao-Gui, Sun Cheng

机构信息

Sate Key Laboratory of Pollution Control and Resource Reuse, School of the Environment, Nanjing University, Nanjing 210093, China.

出版信息

Huan Jing Ke Xue. 2009 Jun 15;30(6):1756-61.

Abstract

The sorption-desorption experiments of the herbicide mefenacet on five soils with different physicochemical properties were conducted using bath equilibrium methods, and the effects of soil organic matter and pH value on sorption of this herbicide were also investigated. The results showed that the sorption and desorption behaviors of mefenacet on soils could be well described by both the linear model and Freundlich model. Sorption distribution coefficients K(oc) for five tested soil are between 849.5 L x kg(-1) and 1 818.8 L x kg(-1), which shows that mefenacet can be well adsorbed on soils. It is found that the sorption coefficients, K(d), K(f), and K(f) (1/n) had good correlation with organic matter content (OM) in soils. It is obviously suggested that organic matter was the dominant factor affecting the sorption of mefenacet on soils. For the same soil, the sorption amount of mefenacet decreased with the increase of pH value. The desorption hysteresis of mefenacet was revealed in the single-cycle sorption and desorption experiments, which indicated a weak transferability of this herbicide in soils.

摘要

采用恒温振荡平衡法研究了除草剂苯噻酰草胺在5种理化性质不同的土壤上的吸附-解吸特性,探讨了土壤有机质和pH值对该除草剂吸附的影响。结果表明,苯噻酰草胺在土壤上的吸附和解吸行为均可用线性模型和Freundlich模型很好地描述。5种供试土壤的吸附分配系数K(oc)在849.5 L·kg-1至1 818.8 L·kg-1之间,表明苯噻酰草胺在土壤上具有较强的吸附能力。土壤吸附系数K(d)、K(f)和K(f)(1/n)与土壤有机质含量(OM)具有显著的相关性,表明土壤有机质是影响苯噻酰草胺吸附的主要因素。同一土壤中,苯噻酰草胺的吸附量随pH值的升高而降低。单循环吸附-解吸试验显示了苯噻酰草胺的解吸滞后现象,表明该除草剂在土壤中的迁移性较差。

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