Department of Chemical Engineering, Center for Chemical Sensors Development, University of Puerto Rico-Mayagüez, Mayagüez, PR 00681-9046.
Chemosphere. 2009 Oct;77(4):546-51. doi: 10.1016/j.chemosphere.2009.07.008. Epub 2009 Aug 6.
The fate and transport of TNT has been studied as part of a research program to develop chemical sensors for detecting landmines. The spatial and temporal concentration profiles of TNT and its degradation products depend primarily on the mobility of the water phase. The fate and transport of TNT released from a mine determine the location of the maximum concentration of chemicals on the surface. Chemical detection on the other hand may also provide such spatial location, but the actual position of the landmine is not necessary under the surface of that point. Although this hypothesis seems logical, it has never been proven. This paper presents numerical simulations in 3D (using LaGriT and FEHM codes developed at Los Alamos National Laboratories) of the fate and transport of TNT released from a landmine under changing environmental conditions (such as rainfall and solar radiation). To assess the numerical techniques, we compare numerical simulations to experimental data previously obtained.
TNT 的命运和迁移已作为开发地雷化学传感器研究计划的一部分进行了研究。TNT 及其降解产物的时空浓度分布主要取决于水相的迁移能力。地雷释放的 TNT 的命运和迁移决定了表面上化学物质最大浓度的位置。另一方面,化学检测也可以提供这种空间位置,但在该点下方的地雷实际位置并不必要。尽管这一假设似乎合乎逻辑,但从未得到证实。本文使用洛斯阿拉莫斯国家实验室开发的 LaGriT 和 FEHM 代码在 3D 中进行了数值模拟(TNT 在变化的环境条件(如降雨和太阳辐射)下从地雷中释放的命运和迁移)。为了评估数值技术,我们将数值模拟与之前获得的实验数据进行了比较。