离子-分子反应揭示了肽中自由基的易位。
Ion-molecule reactions reveal facile radical migration in peptides.
作者信息
Moore Benjamin N, Blanksby Stephen J, Julian Ryan R
机构信息
Department of Chemistry, University of California Riverside, Riverside, CA, USA.
出版信息
Chem Commun (Camb). 2009 Sep 7(33):5015-7. doi: 10.1039/b907833a. Epub 2009 Jul 13.
DOI:10.1039/b907833a
PMID:19668834
Abstract
Ion-molecule reactions between molecular oxygen and peptide radicals in the gas phase demonstrate that radical migration occurs easily within large biomolecules without addition of collisional activation energy.
摘要
气相中分子氧与肽自由基之间的离子-分子反应表明，在不添加碰撞活化能的情况下，自由基迁移能在大型生物分子中轻易发生。
Zotero 插件