Izarova Natalya V, Dickman Michael H, Biboum Rosa Ngo, Keita Bineta, Nadjo Louis, Ramachandran Vasanth, Dalal Naresh S, Kortz Ulrich
Jacobs University, School of Engineering and Science, P.O. Box 750 561, 28725 Bremen, Germany.
Inorg Chem. 2009 Aug 17;48(16):7504-6. doi: 10.1021/ic900953a.
Two discrete anionic palladium(II)-oxo clusters have been prepared: Pd(13)(As(V)Ph)(8)O(32) (1) and Pd(13)Se(IV)(8)O(32) (2) were synthesized in one-pot self-assembly reactions of Pd(OAc)(2) with PhAsO(3)H(2) and SeO(2) and characterized by single-crystal X-ray analysis, IR, thermogravimetric analysis, elemental analysis, magnetic and electron paramagnetic resonance measurements, and electrochemistry.
已制备出两种离散的阴离子钯（II）-氧簇合物：Pd(13)(As(V)Ph)(8)O(32)（1）和Pd(13)Se(IV)(8)O(32)（2），它们是通过Pd(OAc)(2)与PhAsO(3)H(2)和SeO(2)的一锅自组装反应合成的，并通过单晶X射线分析、红外光谱、热重分析、元素分析、磁性和电子顺磁共振测量以及电化学进行了表征。
