Lan Anjian, Li Kunhao, Wu Haohan, Kong Lingzhu, Nijem Nour, Olson David H, Emge Thomas J, Chabal Yves J, Langreth David C, Hong Maochun, Li Jing
Department of Chemistry and Chemical Biology, Rutgers, The State University of New Jersey, Piscataway, New Jersey 08854, USA.
Inorg Chem. 2009 Aug 3;48(15):7165-73. doi: 10.1021/ic9002115.
A microporous metal organic framework structure, Zn(2)(bpdc)(2)(bpee).2DMF (DMF: N,N-dimethylformamide), has been synthesized via solvothermal reactions. The compound is a new member of the RPM series (RPM = Rutgers Recyclable Porous Material) that possesses a flexible and recyclable three-dimensional framework containing one-dimensional channels. It exhibits interesting and multifold functionality, including porosity, commensurate adsorption for hydrocarbons, high hydrogen binding energy (determined by isosteric heats of hydrogen adsorption and confirmed by van der Waals density functional calculations) as a result of multifold binding to aromatic ligands (determined by IR spectroscopy), strong photoluminescence emission, and reversible fluorescence quenching properties.
一种微孔金属有机骨架结构Zn(2)(bpdc)(2)(bpee).2DMF（DMF：N，N - 二甲基甲酰胺）已通过溶剂热反应合成。该化合物是RPM系列（RPM = 罗格斯可回收多孔材料）的新成员，具有包含一维通道的柔性且可回收的三维骨架。它展现出有趣且多样的功能，包括孔隙率、对碳氢化合物的适度吸附、由于与芳香配体多重结合（通过红外光谱确定）而具有的高氢结合能（由氢吸附等量热确定并经范德华密度泛函计算证实）、强的光致发光发射以及可逆的荧光猝灭特性。
