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四个联邦应急管理局临时住房单元中的甲醛及其他挥发性有机化合物排放情况

Formaldehyde and other volatile organic chemical emissions in four FEMA temporary housing units.

作者信息

Maddalena Randy, Russell Marion, Sullivan Douglas P, Apte Michael G

机构信息

Indoor Environment Department, Environmental Energy Technologies Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Road (Mail Stop 70-108b), Berkeley, California 94720, USA.

出版信息

Environ Sci Technol. 2009 Aug 1;43(15):5626-32. doi: 10.1021/es9011178.

Abstract

Indoor concentrations of 33 volatile organic chemicals were measured in four unoccupied temporary housing units (THUs) belonging to the U.S. Federal Emergency Management Administration (FEMA). The highest level contaminants in the THUs include formaldehyde, acetic acid, and 2,2,4-trimethyl-1,3-pentanediol diisobutyrate (TXIB) with median concentrations of 440, 425, and 36 ppb, respectively. A number of volatile organic compounds (VOCs) were higher than published concentrations in other dwellings, but whole THU emission factors for most chemicals were either lower than or similar to values reported for newly constructed homes. However, several chemicals exceeded previously measured new building emission rates by over a factor of 5. Materials were collected from the THUs, and emission factors were determined using small chambers to identify the potential source of indoor contaminants. The individual materials were grouped by material type, and emissions were used to derive exposure concentrations for comparison to reference values. Using material loading factors and ventilation rates that are relevant to the trailers, all of the material types we tested had at least two chemicals (formaldehyde and nonanal) with derived concentrations in excess of chronic reference exposure levels or odor thresholds. The extensive use of composite wood products, sealants, and vinyl coverings, combined with the low air exchange rates relative to material surface areas, may explain the high concentrations of some VOCs and formaldehyde.

摘要

在美国联邦紧急事务管理局(FEMA)所属的四个无人居住的临时住房单元(THU)中,测量了33种挥发性有机化合物的室内浓度。临时住房单元中含量最高的污染物包括甲醛、乙酸和2,2,4-三甲基-1,3-戊二醇二异丁酸酯(TXIB),其浓度中值分别为440 ppb、425 ppb和36 ppb。一些挥发性有机化合物(VOC)的浓度高于其他住宅公布的浓度,但大多数化学品的整个临时住房单元排放因子低于或类似于新建房屋报告的值。然而,有几种化学品超过了先前测量的新建建筑排放率5倍以上。从临时住房单元收集了材料,并使用小型试验箱确定排放因子,以识别室内污染物的潜在来源。将单个材料按材料类型分组,并利用排放来推导暴露浓度,以便与参考值进行比较。使用与拖车相关的材料装载因子和通风率,我们测试的所有材料类型都至少有两种化学品(甲醛和壬醛),其推导浓度超过慢性参考暴露水平或气味阈值。复合木制品、密封剂和乙烯基覆盖物的大量使用,再加上相对于材料表面积较低的空气交换率,可能解释了一些挥发性有机化合物和甲醛的高浓度。

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