Song Huikang, Xu Leilei, Chen Mindong, Cui Yan, Wu Cai-E, Qiu Jian, Xu Liang, Cheng Ge, Hu Xun
Collaborative Innovation Centre of the Atmospheric Environment and Equipment Technology, School of Environmental Science and Engineering, Nanjing University of Information Science & Technology, Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control Nanjing 210044 P. R. China
College of Light Industry and Food Engineering, Nanjing Forestry University Nanjing 210037 P. R. China.
RSC Adv. 2021 Nov 3;11(56):35494-35513. doi: 10.1039/d1ra06497e. eCollection 2021 Oct 28.
Nanostructured MnO with various morphologies exhibits excellent performance in environmental catalysis owing to its large specific surface area, low density, and adjustable chemical properties. The one-dimensional MnO nanowire has been proved to be the dominant morphology among various nanostructures, such as nanorods, nanofibers, nanoflowers, . The syntheses and applications of MnO-based nanowires also have become a research hotspot in environmental catalytic materials over the last two decades. With the continuous deepening of the research, the control of morphology and crystal facet exposure in the synthesis of MnO nanowire materials have gradually matured, and the catalytic performance also has been greatly improved. Differences in the crystalline phase structure, preferably exposed crystal facets, and even the length of the MnO nanowires will evidently affect the final catalytic performances. Besides, the modifications by doping or loading will also significantly affect their catalytic performances. This review carefully summarizes the synthesis strategies of MnO nanowires developed in recent years as well as the influences of the phase structure, crystal facet, morphology, dopant, and loading amount on the catalytic performance. Besides, the cutting-edge applications of MnO nanowires in the field of environmental catalysis, such as CO oxidation, the removal of VOCs, denitrification, ., have been also summarized. The application of MnO nanowire in environmental catalysis is still in the early exploratory stage. The gigantic gap between theoretical investigation and industrial application is still a great challenge. Compared with noble metal based traditional environmental catalytic materials, the lower cost of MnO has injected new momentum and promising potential into this research field.
具有各种形态的纳米结构MnO由于其大比表面积、低密度和可调节的化学性质,在环境催化中表现出优异的性能。一维MnO纳米线已被证明是各种纳米结构(如纳米棒、纳米纤维、纳米花等)中的主要形态。在过去二十年中,基于MnO的纳米线的合成和应用也已成为环境催化材料领域的一个研究热点。随着研究的不断深入,MnO纳米线材料合成中形态和晶面暴露的控制已逐渐成熟,催化性能也得到了极大提高。MnO纳米线的晶相结构、择优暴露的晶面甚至长度的差异都会明显影响最终的催化性能。此外,通过掺杂或负载进行的改性也会显著影响其催化性能。本综述仔细总结了近年来开发的MnO纳米线的合成策略以及相结构、晶面、形态、掺杂剂和负载量对催化性能的影响。此外,还总结了MnO纳米线在环境催化领域的前沿应用,如CO氧化、VOCs去除、脱硝等。MnO纳米线在环境催化中的应用仍处于早期探索阶段。理论研究与工业应用之间的巨大差距仍然是一个巨大的挑战。与基于贵金属的传统环境催化材料相比,MnO较低的成本为该研究领域注入了新的动力和广阔的潜力。