Baysal Senay Hamarat, Onal Secil, Ozdemir Guven
Biochemistry Department, Faculty of Science, Ege University, Bornova-Izmir, Turkey.
Prep Biochem Biotechnol. 2009;39(4):419-28. doi: 10.1080/10826060903209794.
In this work, the potential use of the immobilized cells of Chryseomonas luteola TEM 05 for the removal of Cr(+6), Cd(+2) and Co(+2) ions from aqueous solutions was investigated. The living cells of C. luteola TEM 05 were firstly entrapped both in carrageenan and chitosan coated carrageenan gels and then used in biosoption of the metal ions in batch reactors at pH 6.0, 25 degrees C, in 100 mg L(-1) of each metal solution. Besides this, a process of competitive biosorption of these metal ions was also described and compared to single metal ion adsorption in solution. According to the immobilization results, the replacement of KCl by KCl-chitosan as gelling agent improved the mechanical strength and thermal stability of the gel. In addition, the C. luteola TEM 05 immobilized carrageenan-chitosan gel system was quite more efficient for the fast adsorption of metal ions from aqueous solution than the carrageenan gels without biomass.
在这项工作中,研究了固定化的淡黄 Chryseomonas luteola TEM 05 细胞从水溶液中去除 Cr(+6)、Cd(+2) 和 Co(+2) 离子的潜在用途。首先将淡黄 Chryseomonas luteola TEM 05 的活细胞包埋在卡拉胶和壳聚糖包被的卡拉胶凝胶中,然后在 pH 6.0、25 摄氏度、每种金属溶液浓度为 100 mg L(-1) 的条件下,用于间歇式反应器中金属离子的生物吸附。此外,还描述了这些金属离子的竞争性生物吸附过程,并与溶液中的单一金属离子吸附进行了比较。根据固定化结果,用 KCl-壳聚糖替代 KCl 作为胶凝剂提高了凝胶的机械强度和热稳定性。此外,与没有生物质的卡拉胶凝胶相比,固定化淡黄 Chryseomonas luteola TEM 05 的卡拉胶-壳聚糖凝胶体系从水溶液中快速吸附金属离子的效率要高得多。