Pościk Adam, Wandelt Barbara
Central Institute for Labour Protection - National Research Institute (CIOP-PIB), Łódź, Poland.
Int J Occup Saf Ergon. 2009;15(3):243-54. doi: 10.1080/10803548.2009.11076805.
The main purposes of this study were to select a photochromic dye and to develop an active welding filter with a photochromic layer. A series of functionalized spirobenzopyranoindolins were synthesized and their photophysical and photochemical properties were investigated in a solution using absorption and emission spectroscopy. Time-resolved fluorescence spectroscopy measurements were used to characterize the decays and rate constants of fluorescence emission. One dye was selected as a suitable photoactive compound in automatic welding filters. A model of an active welding filter with a photochromic layer based on 1',3',3'-trimethyl-6-nitrospiro[2H-1-benzopyran-2,2'-indole] (6-nitroBIPS) was developed. The paper presents the results of tests of the filter conducted according to EN standards.
本研究的主要目的是选择一种光致变色染料,并开发一种带有光致变色层的有源焊接滤光片。合成了一系列功能化的螺苯并吡喃吲哚啉,并使用吸收光谱和发射光谱在溶液中研究了它们的光物理和光化学性质。时间分辨荧光光谱测量用于表征荧光发射的衰减和速率常数。选择了一种染料作为自动焊接滤光片中合适的光活性化合物。开发了一种基于1',3',3'-三甲基-6-硝基螺[2H-1-苯并吡喃-2,2'-吲哚](6-硝基BIPS)的带有光致变色层的有源焊接滤光片模型。本文介绍了根据EN标准对该滤光片进行测试的结果。