V. Cermák Laboratory, J. Heyrovský Institute of Physical Chemistry, v.v.i., Academy of Sciences of the Czech Republic, Dolejskova 3, 182 23 Prague 8, Czech Republic.
J Phys Chem A. 2009 Dec 31;113(52):14838-44. doi: 10.1021/jp904995p.
Survival probabilities, S(a) (%), of hydrocarbon ions C1, C2, and C3 and several nonhydrocarbon ions (Ar(+), N(2)(+), CO(2)(+)) on room-temperature (hydrocarbon-covered) and heated (600 degrees C) surfaces of carbon (HOPG), tungsten, and beryllium were experimentally determined using the ion-surface scattering method for several incident energies from a few electronvolts up to about 50 eV and for the incident angle of 30 degrees (with respect to the surface). A simple correlation between S(a) and the ionization energy (IE) of the incident ions was found in the semilogarithmic plot of S(a) versus IE. The plots of the data at 31 eV were linear for all studied surfaces and could be fitted by an empirical equation log S(a) = a - b(IE). The values of the parameters a and b were determined for all investigated room-temperature and heated surfaces and can be used to estimate unknown survival probabilities of ions on these surfaces from their ionization energies.
用离子-表面散射法,在室温(烃覆盖)和加热(600°C)条件下,对碳原子(HOPG)、钨和铍表面的烃离子 C1、C2 和 C3 以及几种非烃离子(Ar(+)、N(2)(+)、CO(2)(+)),在几个从几电子伏特到约 50 电子伏特的入射能和 30 度入射角下,实验测定了它们的存活概率 S(a)(%)。在 S(a)对入射离子电离能(IE)的半对数图中,发现 S(a)与 IE 之间存在简单的相关性。在所有研究的表面上,31 eV 时的数据图呈线性,可用经验公式 log S(a) = a - b(IE)拟合。确定了所有研究的室温及加热表面的参数 a 和 b 的值,可用于根据这些表面上离子的电离能来估计它们的未知存活概率。