钯/烷基亚磷酸酯-硫酸盐催化剂对醋酸乙烯酯与乙烯的共聚反应。
Copolymerization of vinyl acetate with ethylene by palladium/alkylphosphine-sulfonate catalysts.
机构信息
Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku 113-8656, Japan.
出版信息
J Am Chem Soc. 2009 Oct 21;131(41):14606-7. doi: 10.1021/ja9050839.
PMID:19785406
Abstract
Coordination copolymerization of vinyl acetate (VAc) with ethylene, leading to linear copolymers that possess in-chain -CH(2)CH(OAc)- units, has been accomplished using novel palladium complexes bearing alkylphosphine-sulfonate ligands.
摘要
采用新型钯配合物作为催化剂，通过乙烯与醋酸乙烯酯的配位共聚反应，得到了具有链段式-CH(2)CH(OAc)-单元的线性共聚物。
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