Nolde Moana, Weitzel Karl-Michael, Western Colin M
Philipps-Universität Marburg, Fachbereich, Hans-Meerwein-Strasse, 35032 Marburg, Germany.
Phys Chem Chem Phys. 2005 Apr 7;7(7):1527-32. doi: 10.1039/b417835c.
The C' Rydberg states of the ammonia isotopomers NH3, NH2D, NHD2 and ND3 have been investigated by (2 + 1) resonance enhanced multiphoton ionisation spectroscopy. The spectroscopic parameters for the zero point and v'2 = 1 vibrational levels of the C' 1A'1 state have been derived for the first time for the mixed isotopomers. The current work provides the basis for future studies of the chemical reactions of the mixed isotopomers of ammonia ions formed by the REMPI technique.
通过（2 + 1）共振增强多光子电离光谱法研究了氨同位素异构体NH3、NH2D、NHD2和ND3的C'里德堡态。首次推导了混合同位素异构体C' 1A'1态零点和v'2 = 1振动能级的光谱参数。目前的工作为未来研究由共振增强多光子电离技术形成的氨离子混合同位素异构体的化学反应提供了基础。
