通过钯催化的碳醚化反应合成多取代四氢呋喃
Synthesis of polysubstituted tetrahydrofurans via Pd-catalyzed carboetherification reactions.
作者信息
Hay Michael B, Wolfe John P
机构信息
University of Michigan, Department of Chemistry, 930 N. University Ave, Ann Arbor, Michigan, 48109-1055.
出版信息
Tetrahedron Lett. 2006 Apr 17;47(16):2793-2796. doi: 10.1016/j.tetlet.2006.02.066.
Abstract
Pd-catalyzed carboetherifications of 1-, 2-, or 3-substituted γ-hydroxy internal alkenes afford tetrahydrofuran products bearing three stereocenters in good yield with moderate to good stereoselectivity.
摘要
钯催化的1-、2-或3-取代的γ-羟基内烯烃的碳醚化反应能够以良好的产率和中等至良好的立体选择性得到带有三个立体中心的四氢呋喃产物。
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