McMahon Jeffrey M, Gray Stephen K, Schatz George C
Department of Chemistry, Northwestern University, Evanston, Illinois 60208, USA.
Phys Rev Lett. 2009 Aug 28;103(9):097403. doi: 10.1103/PhysRevLett.103.097403. Epub 2009 Aug 27.
We present an implementation of Maxwell's equations that incorporates the spatially nonlocal response of materials, an effect necessary to describe the optical properties of structures with features less than 10 nm. For the first time it is possible to investigate the nonlocal optical response of structures without spherical or planar shape, and outside of the electrostatic limit. As an illustration, we calculate the optical properties of Au nanowires and show that nonlocal effects are particularly important in structures with apex features, even for arbitrarily large sizes.
我们展示了麦克斯韦方程组的一种实现方式,它纳入了材料的空间非局部响应,这是描述特征尺寸小于10纳米的结构光学特性所必需的一种效应。首次有可能研究非球形或非平面形状且超出静电极限的结构的非局部光学响应。作为一个例证,我们计算了金纳米线的光学特性,并表明非局部效应在具有尖端特征的结构中尤为重要,即使对于任意大的尺寸也是如此。