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电感耦合等离子体质谱法在木薯副产品中矿物元素和重金属检测中的应用

[Application of ICP-MS to detection of mineral elements and heavy metals in Cassava's byproducts].

作者信息

Tao Hai-Teng, Zhang Chun-Jiang, Chen Xiao-Ming, Lüi Fei-Jie, Tai Jian-Xiang, Li Kai-Mian

机构信息

College of Food Science and Nutritional Engineering, China Agricultural University, Beijing 100083, China.

出版信息

Guang Pu Xue Yu Guang Pu Fen Xi. 2009 Jul;29(7):1983-5.

Abstract

Cassava is a main cultivated tropical crop in China, its rich starch roots are often used to produce fuel ethanol in recent years, so it's a kind of hot biomass energy crops. But cassava's byproducts such as leaves, stems and peels are regarded as waste, and are not fully utilized. Cassava's byproducts contain many nutrients, and can be used to process high value food products. The contents of mineral elements and heavy metals in cassava's byproducts were studied by ICP-MS. The results showed that cassava's byproducts contained many elements necessary to human health, the sequence of macroelements was K>Ca>P> Mg>S>Mn>Zn>Na>Fe>B>Cu, particularly, the contents of Fe, Mn, Zn and B ranged from 10 to 800 microg x g(-1) (DW), while the contents of microelements including Mo, Co, Se and Ge ranged from 0.01 to 0.2 microg x g(-1) (DW), which are important to human health. Besides macroelements and microelements, the contents of heavy metals (As, Cr, Pb and Hg) were also important to identify the quality of farm products, and the results showed that cassava's byproducts contained little heavy metals except Pb (2.19 microg x g(-1) (DW) in stalk peels). All the data showed that cassava's byproducts accorded with the national hygiene standards.

摘要

木薯是中国主要种植的热带作物,其富含淀粉的块根近年来常被用于生产燃料乙醇,因此它是一种热门的生物质能源作物。但木薯的叶、茎和皮等副产品被视为废弃物,未得到充分利用。木薯副产品含有多种营养成分,可用于加工高附加值食品。采用电感耦合等离子体质谱法(ICP-MS)研究了木薯副产品中矿质元素和重金属的含量。结果表明,木薯副产品含有许多人体健康所需的元素,常量元素顺序为K>Ca>P>Mg>S>Mn>Zn>Na>Fe>B>Cu,特别是Fe、Mn、Zn和B的含量在10至800μg·g⁻¹(干重)之间,而Mo、Co、Se和Ge等微量元素的含量在0.01至0.2μg·g⁻¹(干重)之间,这些对人体健康很重要。除了常量元素和微量元素外,重金属(As、Cr、Pb和Hg)的含量对农产品质量鉴定也很重要,结果表明,木薯副产品中除了茎皮中的Pb(2.19μg·g⁻¹(干重))外,重金属含量很少。所有数据表明,木薯副产品符合国家卫生标准。

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