手性单体的立规聚合：聚合物合成中序列控制的新方法。
Polymerization of enantiopure monomers using syndiospecific catalysts: a new approach to sequence control in polymer synthesis.
机构信息
Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York, 14853-1301, USA.
出版信息
J Am Chem Soc. 2009 Nov 11;131(44):16042-4. doi: 10.1021/ja9075327.
PMID:19835375
Abstract
The ring-opening polymerization of a mixture of enantiomerically pure but different monomers using an yttrium complex as initiator proceeds readily at room temperature to give the corresponding highly alternating polyester.
摘要
用钇络合物作为引发剂，使对映纯但不同单体的混合物开环聚合，在室温下很容易进行，得到相应的高度交替聚酯。
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