Department of Chemical Engineering, Technion, Haifa 32000, Israel.
Langmuir. 2009 Nov 17;25(22):12837-42. doi: 10.1021/la902578j.
We present numerical simulations of three-dimensional liquid bridges between two identical smooth and chemically homogeneous cylinders held at a fixed distance and angle one with respect to the other. Despite the limited range of parameters studied, an analysis of resultant forces, energies, and torques reveals a rich level of detail. For large enough separations between the cylinders, the bridges appear symmetric and stable in shape and are found to yield a negligible torque on the cylinders. The force of adhesion is found to be positive in this case (the cylinders are attracted one to the other). A reduction in the distance between the cylinders reveals different behavior depending on the particular value of the set of parameters considered. For example, it appears that while relatively low contact angle systems favor attractive (positive) forces and stable symmetric bridges for small separation distances, larger contact angles lead to the coexistence of stable asymmetric and (apparently) unstable symmetric solutions, mostly (and respectively) associated with near-zero and negative (repulsive) forces of adhesion. In addition, while the larger values of contact angles studied here (90 degrees, 110 degrees) are associated with barely detectable torques, smaller values of contact angle are found to be associated with torques acting to rotate cylinders into a position where they are parallel one with respect to the other.
我们呈现了两个相同的光滑、化学均匀的圆柱体之间的三维液体桥的数值模拟,这两个圆柱体保持固定的距离和角度。尽管研究的参数范围有限,但对产生的力、能量和扭矩的分析揭示了丰富的细节。对于两个圆柱体之间足够大的分离距离,桥梁呈现出对称和稳定的形状,并且发现对圆柱体的扭矩可以忽略不计。在这种情况下,粘附力为正(圆柱体相互吸引)。减小圆柱体之间的距离会根据所考虑的参数集的特定值呈现出不同的行为。例如,似乎相对较低的接触角系统有利于吸引力(正力)和小分离距离下稳定的对称桥梁,而较大的接触角导致稳定的不对称和(显然)不稳定的对称解共存,主要与接近零和负(排斥)粘附力相关。此外,虽然这里研究的较大接触角值(90 度、110 度)与几乎不可检测的扭矩相关,但是较小的接触角值被发现与扭矩有关,扭矩作用于将圆柱体旋转到彼此平行的位置。