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从放射性溶液中用泥炭藓保留铀酰离子和钍离子。

On the retention of uranyl and thorium ions from radioactive solution on peat moss.

机构信息

Faculty of Chemistry, AlI Cuza University of Iasi, Bd 11 Carol I Boulevard, 700506 Iasi, Romania.

出版信息

J Hazard Mater. 2010 Feb 15;174(1-3):782-7. doi: 10.1016/j.jhazmat.2009.09.120. Epub 2009 Sep 30.

Abstract

The efficiency of the radioactive uranyl and thorium ions on the peat moss from aqueous solutions has been investigated under different experimental conditions. The sorption and desorption of uranyl and thorium ions on three types (unmodified peat moss, peat moss treated with HNO(3) and peat moss treated with NaOH) of peat moss were studied by the static method. Peat moss was selected as it is available in nature, in any amount, as a cheap and accessible sorbent. Study on desorption of such ions led to the conclusion that the most favourable desorptive reagent for the uranyl ions is Na(2)CO(3) 1M while, for the thorium ions is HCl 1M. The results obtained show that the parameters here under investigation exercise a significant effect on the sorption process of the two ions. Also, the investigations performed recommend the peat moss treated with a base as a potential sorbent for the uranyl and thorium ions from a radioactive aqueous solution.

摘要

已在不同实验条件下研究了放射性铀酰和钍离子在来自水溶液的泥炭藓中的效率。通过静态法研究了三种类型(未改性的泥炭藓、用 HNO3 处理的泥炭藓和用 NaOH 处理的泥炭藓)的泥炭藓对铀酰和钍离子的吸附和解吸。选择泥炭藓是因为它在自然界中大量存在,作为一种廉价且易得的吸附剂。对这些离子的解吸研究得出的结论是,对于铀酰离子,最有利的解吸试剂是 1M 的 Na2CO3,而对于钍离子,则是 1M 的 HCl。研究结果表明,在此研究的参数对两种离子的吸附过程有显著影响。此外,所进行的研究推荐使用碱性处理的泥炭藓作为放射性水溶液中铀酰和钍离子的潜在吸附剂。

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