Department of Chemical Engineering, Faculty of Engineering and Architecture, Eskişehir Osmangazi University, Meşelik Campus, 26480 Eskişehir, Turkey.
Bioresour Technol. 2010 Mar;101(6):1675-80. doi: 10.1016/j.biortech.2009.09.087. Epub 2009 Oct 24.
In this study, activated carbons were prepared from sugar beet bagasse by chemical activation and the prepared activated carbons were used to remove nitrate from aqueous solutions. In chemical activation, ZnCl(2) was used as chemical agent. The effects of impregnation ratio and activation temperature were investigated. The produced activated carbons were characterized by measuring their porosities and pore size distributions. The microstructure of the activated carbons was examined by scanning electron microscopy (SEM). The maximum specific surface area of the activated carbon was about 1826m(2)/g at 700 degrees C and at an impregnation ratio of 3:1. The resulting activated carbon was used for removal of nitrate from aqueous solution. The effects of pH, temperature and contact time were investigated. Isotherm studies were carried out and the data were analyzed by Langmuir, Freundlich and Temkin equations. Three simplified kinetic models were tested to investigate the adsorption mechanism.
在这项研究中,我们通过化学活化法从糖甜菜渣中制备了活性炭,并将制备的活性炭用于去除水溶液中的硝酸盐。在化学活化中,我们使用了 ZnCl(2)作为化学试剂。研究了浸渍比和活化温度的影响。通过测量比表面积和孔隙率来对所制备的活性炭进行了表征。通过扫描电子显微镜(SEM)观察了活性炭的微观结构。在浸渍比为 3:1、活化温度为 700°C 时,活性炭的最大比表面积约为 1826m(2)/g。所得活性炭用于去除水溶液中的硝酸盐。考察了 pH 值、温度和接触时间的影响。进行了等温线研究,并通过 Langmuir、Freundlich 和 Temkin 方程对数据进行了分析。测试了三个简化的动力学模型来研究吸附机制。