Szczurek Andrzej, Maciejewska Monika, Flisowska-Wiercik Barbara, Bodzoj Lukasz
Faculty of Environmental Engineering, Wrocław University of Technology, Wyb. Wyspiańskiego 27, 50-370, Wrocław, Poland.
J Environ Monit. 2009 Nov;11(11):1942-51. doi: 10.1039/b907820g. Epub 2009 Jul 31.
This work aims at estimating the ability of a sensor system to recognize the type and to determine the concentration of organic compounds emitted from solvents. The measuring system used in the experiment consisted of a sensor array and a unit for data analysis. Commercially available sensors (Figaro, TGS) were used as a basis for the construction of the first of the two elements. The second element utilized Discriminant Function Analysis (DFA) and Multiple Linear Regression (MLR). The investigated gas samples consisted of air mixed with variable amounts of two organic compounds. One of the two compounds was intended to have a dominant influence on the sensors' response. Depending on this substance, two groups of gaseous mixtures were considered. In the first one, hexane was the major compound. The choice of this particular group of chemical compositions was inspired by practical problems related to various applications of extraction solvents. In the case of the second group of gas mixtures, the prevailing compound was toluene. This type of mixture, on the other hand, is related to the use of paints. The data analysis unit was designed to achieve the following two goals: in the first place, to recognize binary gas mixtures and secondly, to determine the concentrations of VOCs in them. The data analysis was based on steady-state sensor responses. Our study demonstrates that the sensor system may be employed for classifying and quantitatively determining volatile organic compounds released into air as a result of the use of solvents. The presented solution proves the concept in the case of binary mixtures of VOCs.
这项工作旨在评估一种传感器系统识别从溶剂中释放出的有机化合物类型并确定其浓度的能力。实验中使用的测量系统由一个传感器阵列和一个数据分析单元组成。市售传感器(费加罗,TGS)被用作构建这两个元件中第一个元件的基础。第二个元件采用判别函数分析(DFA)和多元线性回归(MLR)。所研究的气体样本由与不同量的两种有机化合物混合的空气组成。这两种化合物中的一种旨在对传感器的响应产生主要影响。根据这种物质,考虑了两组气体混合物。在第一组中,己烷是主要化合物。选择这一特定化学组成组的灵感来自与萃取溶剂各种应用相关的实际问题。在第二组气体混合物中,主要化合物是甲苯。另一方面,这种类型的混合物与涂料的使用有关。数据分析单元旨在实现以下两个目标:首先,识别二元气体混合物;其次,确定其中挥发性有机化合物(VOCs)的浓度。数据分析基于传感器的稳态响应。我们的研究表明,该传感器系统可用于对因使用溶剂而释放到空气中的挥发性有机化合物进行分类和定量测定。所提出的解决方案在VOCs二元混合物的情况下证明了这一概念。